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Description
The design of a field-scale injection of engineered nanoparticle (NP) suspensions for the remediation of a polluted site requires the development of quantitative predictive models for the system design and implementation.
In general, micro- and nanoparticle transport in porous media is controlled by particle-particle and particle-porous media interactions, which are in turn affected by flow velocity and pore water chemistry. During the injection, a strong perturbation of the flow field is induced around the well, and the particle transport is mainly controlled by the consequent sharp variation of pore-water velocity, and by the hydro-chemical properties of the injected fluid. Conversely, when the injection is stopped, the particles are transported solely due to the natural flow, and the influence of groundwater geochemistry (ionic strength, IS, in particular) on the particle behaviour becomes predominant. Pore-water velocity and IS are therefore important parameters influencing particle transport in groundwater, and have to be taken into account by the numerical codes used to support nanoremediation design.
Several analytical and numerical tools have been developed in recent years to model the transport of colloidal particles in simplified geometry and boundary conditions. For instance, the numerical tool MNMs was developed by the authors of this work to simulate colloidal transport in 1D Cartesian and radial coordinates. Only few simulation tools are instead available for 3D colloid transport, and none of them implements direct correlations accounting for variations of groundwater IS and flow velocity.
In this work a new modelling tool, MNM3D (Micro and Nanoparticles transport Model in 3D geometries), is proposed for the simulation of injection and transport of nanoparticle suspensions in generic complex scenarios. MNM3D implements a new formulation to account for the simultaneous dependency of the attachment and detachment kinetic coefficients on groundwater IS and velocity. The software was developed in the framework of the FP7 European research project NanoRem and can be used to predict the NP mobility at different stages of a nanoremediation application, both in the planning and design stages (i.e. support the design of the injection plan), and later to predict the long-term particle mobility after injection (i.e. support the prediction of final fate of the injected particles). The application of the model in the framework of a novel approach for risk assessment at particle-contaminated sites is also reported.
References
Bianco, C., Tosco, T. & Sethi, R. (2016) Journal of Contaminant Hydrology, 193, p. 10-20.
Ryan, J.N. and Elimelech, M. (1996) Colloids and Surfaces A: Physicochemical and Engineering Aspects 107, 1-56
Tosco, T.; Tiraferri, A.; Sethi, R. Environmental Science & Technology 2009, 43(12), 4425-4431.
Tosco, T.; Gastone, F.; Sethi, R. Journal of Contaminant Hydrology 2014, 166(0), 34-51.
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