Speaker
Description
Capillary imbibition, i.e. the spontaneous flow of a liquid into fine pores and cracks without the assistance of external forces such as gravity, is universal and critically important in many natural processes and industrial applications. On the nanoscale, the intensity of solid–liquid interactions (εS–L), which controls the wettability of the capillary walls, plays a critical role and directly affects the imbibition rate, the shape of the meniscus, the evolution of the dynamic contact angle, and even the viscosity of the confined fluid. Here we use molecular dynamics simulations to systematically investigate how εS–L influences the capillary imbibition dynamics in a nanochannel. We quantify the relationship between the equilibrium contact angles and εS–L, and find that the cosine of equilibrium contact angle increases linearly with εS–L. Subsequently, we investigate the capillary dynamics under a wide range of solid–liquid interactions. We show that the capillary rate increases with εS–L, while an overlarge εS–L may hinder the further growth of the imbibition rate. We also characterize the evolution of the dynamic contact angle, imbibition rate, imbibition length. The findings in this work could provide new insights into the capillary imbibition dynamics on the nanoscale.
Time Block Preference | Time Block A (09:00-12:00 CET) |
---|---|
Acceptance of Terms and Conditions | Click here to agree |