31 May 2021 to 4 June 2021
Europe/Berlin timezone

Swelling beyond Flory

2 Jun 2021, 15:30
15m
Oral Presentation (MS7) Mathematical and numerical methods for multi-scale multi-physics, nonlinear coupled processes MS7

Speaker

Jacques Huyghe (University of Limerick)

Description

Super absorbents are swelling to thousands of percent of strain. Apart from the important industrial applications of these materials, the scientific understanding of electromechanical coupling in these ionized gels are paramount in the scrutiny of mechanotransduction of biological tissue. Regular finite deformation finite element codes fail to simulate these extremely large deformations [6]. A special purpose mixed hybrid finite element code demonstrates its ability to simulate swelling gels down to stiffnesses of 10 kPa, typical for super absorbents [6]. The constitutive modelling of these gels challenges researchers with strong non-linearities [3-5]. The traditional separation of free energy in an elastic, mixing and ionic part is contradicted by experiments [1]. In order to address these issues, new avenues of constitutive modelling are explored [4]. The coupling between electrical and mechanical events may have far-reaching implications in the mechanotransduction phenomena in biological tissues [7]. Indeed, living cells are very well known to respond to electric potential changes and their sensitivity to mechanical load may very well be mediated by electromechanical couplings in the extracellular matrix.

1.Roos, R.W., Petterson, R., Huyghe, J.M. Confined compression and torsion experiments on a pHEMA gel in various bath concentrations Biomech Mod. Mechobiol. 12: 617-626 (2013).
2. Fennel E., Huyghe J.M. Chemically Responsive Hydrogel Deformation
Mechanics: A Review. Molecules 24, 3521; doi:10.3390/molecules24193521 (2019)
3. Fennell E., Kamphus J. and Huyghe J.M. The Importance of the Mixing Energy in Ionized Superabsorbent Polymer Swelling Models. Polymers 2020, 12(3), 609; doi:10.3390/polym12030609
4. Fennel E., Huyghe J.M., Mechano-electrochemical material model of mechanosensing hydrogel at constant volume, Materials and design 198 109340 (2021).
5. Fennell E., Leszczynski S., Kamphus, J. and Huyghe J.M. A strain induced softening and hardening constitutive model for superabsorbent polymers undergoing finite deformation. Int. J. Engng. Sci. ‏ 154 : 103346 (2020)
6. Yu C.; Malakpoor, K.; Huyghe, J. M. Comparing mixed hybrid finite element method with standard FEM in swelling simulations involving extremely large deformations. Comp. Mech. 66 Issue: (2): ‏ 287-309 (2020)
7. Poillot P., Le Maitre C.L. and Huyghe J.M. The Strain-Generated Electrical Potential in Cartilaginous Tissues: A Role for Piezoelectricity. Biophysical Reviews,in press.

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Primary authors

Jacques Huyghe (University of Limerick) Eanna Fennell (University of Limerick) Mr Philip Poillot (Bernal Institute, University of Limerick)

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