19–22 May 2026
Europe/Paris timezone

Pore-Scale Hydrodynamically Driven Trapping of Microplastics in Soils

19 May 2026, 11:35
15m
Oral Presentation (MS02) Environmental Porous Media: Water, Agriculture, and Remediation MS02

Speaker

Marjan Ashrafizadeh (Institute for Geosciences, Applied Geology, Friedrich-Schiller-University Jena, 07749 Jena, Germany)

Description

Microplastic (MP, < 5 mm) pollution is widespread in soils, where particles can persist, migrate with groundwater, and carry harmful chemicals and microorganisms 1-2. Understanding how MPs are transported and retained in porous media is therefore essential for assessing their environmental impacts 3. However, standardized methods to investigate MP transport in soils are still limited 4-5. Most existing studies rely on indirect column experiments, where total retention is estimated from outlet concentrations 6-7. The MP localization is often determined using destructive sampling and chemical extraction, which disturb soil structure and remove important pore-scale information 8-9. Recent studies have shown that X-ray computed tomography (µCT) can be used to visualize MPs in porous media 8-11. However, these studies mainly focused on static systems, where millimeter-sized MP fragments were manually placed in the soil. As a result, the dynamic transport behavior of fine MPs, with sizes of only a few micrometers, remains largely unexplored.
In this study, we introduce a non-destructive pore-scale workflow that combines micro-scale flow-through column experiments with high-resolution X-ray micro-computed tomography (µCT; 0.7–2 µm voxel size) and digital rock physics (DRP) analysis. This integrated approach allows direct three-dimensional visualization and quantitative analysis of the transport and retention of fine MPs (2 µm polystyrene spheres) in soil-relevant porous media. MP suspensions were injected at different flow rates (0.5 to 2 mL min⁻¹) and injection volumes (15 and 30 mL). After injection, the columns were flushed to remove mobile MP particles, dried to stabilize the pore structure, and scanned using µCT. Machine-learning-based segmentation was used to create digital models of the pore space for image-based DRP analysis and interpretation of retention mechanisms.
The results reveal a non-monotonic relationship between flow rate and MP retention, which contradicts predictions from classical colloid filtration theory (Figure 1). Retention decreases as flow rate increases from low to intermediate values. At the highest flow rate, however, retention increases strongly, leading to permeability reductions of up to about 5%. The analyses indicate that at low flow rates, retention is mainly controlled by surface deposition. At intermediate flow rates, advective transport dominates, resulting in lower but more evenly distributed retention. This occurs because increasing the flow rate reduces the time available for particles to approach grain surfaces by Brownian motion, facilitating their transport. At high flow rates, elevated pore-scale velocities force more particles through constricted throats per unit time, increasing particle-particle collisions and interactions with surface roughness. These interactions promote particle clustering and hydrodynamic bridging, as well as trapping of detached MPs from upstream. This interpretation is supported by strong permeability reductions and larger MP clusters observed at high flow rates. This indicates that high-flow events, such as heavy rainfall or irrigation, can cause MPs to accumulate locally in soils rather than continue downward transport. Overall, this study provides clear pore-scale evidence that MP retention depends on flow conditions and improves predictions of their environmental fate.

Figure 1. Effect of flow rate and injected volume on microplastic retention: a) patterns and b) total retention along sand-packed columns.

References 1. Wang, L.; Huang, C.; Cao, J.; Zhou, P.; Han, S.; Qu, G.; Bank, M. S.; Hou, D., Polymer Type, Oxidation, Size, and Abundance of Microplastics in Subsoils versus Topsoils with Varying Land Use in Beijing, China. Environmental Science & Technology 2025. 2. Gao, Y.; Sujathan, S.; Carter, E. A.; Airey, D.; El-Zein, A., Flexible Wall Permeameters for Research on Microplastic Transport in Soil: Validity, Advantages, and Constraints. Environmental Science & Technology 2025, 59 (28), 14585-14596. 3. Xu, H.; Tang, P.; Zhou, Y.; Zhang, Y.; Zhang, T., Effects of pore water flow rate on microplastics transport in saturated porous media: Spatial distribution analysis. Journal of Hazardous Materials 2025, 489, 137511. 4. Lim, S. J.; Lee, K.-J.; Nam, H.; Kim, S. H.; Kim, E.-j.; Lee, S.; Chung, J., Progress and future directions bridging microplastics transport from pore to continuum scale: A comprehensive review for experimental and modeling approaches. TrAC Trends in Analytical Chemistry 2024, 179, 117851. 5. Yang, L.; Zhang, Y.; Kang, S.; Wang, Z.; Wu, C., Microplastics in soil: A review on methods, occurrence, sources, and potential risk. Science of the Total Environment 2021, 780, 146546. 6. Wu, T.; Yang, Z.; Hu, R.; Chen, Y.-F., Three-dimensional visualization reveals pore-scale mechanisms of colloid transport and retention in two-phase flow. Environmental Science & Technology 2023, 57 (5), 1997-2005. 7. Qiao, X.; Qian, S.; Dong, S.; Zhu, D. Z.; Feng, J.; Xu, H.; Zhang, P., Real-time visualization of infiltration and retention of microplastics with different shapes in porous media. Environmental Science & Technology 2024, 58 (47), 21037-21045. 8. Wang, Z.; Li, J.; Qu, Z.; Ayurzana, B.; Zhao, G.; Li, W., Effects of microplastics on the pore structure and connectivity with different soil textures: Based on CT scanning. Environmental Technology & Innovation 2024, 36, 103791. 9. Teles, A.; Almeida, A.; Machado, A.; Oliveira, D.; Lopes, R., CHARACTERIZATION OF MICROPLASTIC PARTICLES IN SANDY SOIL USING X-RAY MICROTOMOGRAPHY. Radiation Physics and Chemistry 2024, 111900. 10. Teles, A.; Silva, M.; Almeida, A.; Machado, A.; Oliveira, D.; Lopes, R., A study of the characterization potential of microplastics embedded in soil applying 3D X-ray microtomography. The European Physical Journal Special Topics 2025, 1-9. 11. Trusler, M. M.; Sturrock, C. J.; Vane, C. H.; Cook, S.; Lomax, B. H., X-ray computed tomography: A novel non-invasive approach for the detection of microplastics in sediments? Marine Pollution Bulletin 2023, 194, 115350.
Country Germany
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Authors

Marjan Ashrafizadeh (Institute for Geosciences, Applied Geology, Friedrich-Schiller-University Jena, 07749 Jena, Germany) Dr Saeid Sadeghnejad (Institute for Geosciences, Applied Geology, Friedrich-Schiller-University Jena, 07749 Jena, Germany)

Co-author

Thorsten Schäfer (Institute for Geosciences, Applied Geology, Friedrich-Schiller-University Jena, 07749 Jena, Germany)

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