22–25 May 2023
Europe/London timezone

Dissolution-precipitation processes: patterns and product separation

25 May 2023, 10:45
1h 30m
Poster Presentation (MS09) Pore-scale modelling Poster

Speaker

Tomasz Szawełło (University of Warsaw)

Description

We consider a porous medium infiltrated by a reactive fluid that triggers coupled dissolution/precipitation reactions at pore surfaces. To study these processes, we model the porous medium as a system of interconnected pipes (Budek, 2012) with the diameter of each segment increasing in proportion to the local reactant consumption. With this model, we investigate different growth regimes in an evolving porous medium, allowing for both erosion and precipitation of the dissolved material. We incorporate nucleation events and consider different models of reactive area evolution, including passivation processes on mineral surfaces. We benchmark the model against the experimental results of Poonoosamy et al. (2020) and then consider
the problem of separation of secondary reaction phases between small and large pores in the medium (Osselin, 2022), elucidating the underlying physical mechanisms.

References

Budek, A., et al. (2012), Network models of dissolution of porous media. Phys. Rev. E, 86, 056318.
Poonoosamy, J., et al. (2020), Effects of solution supersaturation on barite precipitation in porous media and consequences on permeability: Experiments and modelling. Geochim. Cosmochim. Acta., 270: 43-60.
Osselin, F., et al. (2022), Reactive transport experiments of coupled carbonation and serpentinization in a natural serpentinite. Implication for hydrogen production and carbon geological storage. Geochim. Cosmochim. Acta., 318: 165-189.

Participation In-Person
Country Poland
MDPI Energies Student Poster Award No, do not submit my presenation for the student posters award.
Acceptance of the Terms & Conditions Click here to agree

Primary authors

Tomasz Szawełło (University of Warsaw) Prof. Piotr Szymczak (Institute of Theoretical Physics, Faculty of Physics, University of Warsaw, Warsaw, Poland)

Presentation materials

There are no materials yet.