19–22 May 2025
US/Mountain timezone

Anomalous Transport in Porous Environments due to Energy Barriers, Self-Propulsion and Dynamic Confinement

21 May 2025, 08:30
30m
Oral Presentation (MS27) Invited & Plenary Speakers Invited Lecture

Speaker

Daniel Schwartz (University of Colorado Boulder)

Description

The dynamic behavior of molecules and nanoparticles in confined environments, such as at interfaces and within porous materials, lead to complex and highly-varied phenomena, where heterogeneity may arise from spatial variation of the material/interface itself, from structural configurations, or through inhomogeneous dynamic behavior. To obtain relevant information about these complex dynamics, we have developed highly multiplexed single-molecule/single-particle tracking methods that acquire large numbers of trajectories in a given experiment, enabling robust statistical analysis of anomalous motion. Recent work in our lab has explored the 3D motion of both Brownian and self-propelled nanoparticles within highly interconnected porous environments (both static and dynamic), leading to insights linking microscopic pore-scale mechanisms to macroscopic transport. Examples to be discussed include the barrier-limited diffusive escape of nanoparticles from porous cavities, the enhanced motion of self-propelled catalytic Janus particles within 3D porous materials and the facilitated Brownian diffusion of nanoparticles within dynamically fluctuating porous environments.

Country USA
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Primary author

Daniel Schwartz (University of Colorado Boulder)

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