19–22 May 2025
US/Mountain timezone

Capillary trapping and flow dynamics in CO2-Brine systems: A Microfluidic experimental study near the critical point

20 May 2025, 09:35
15m
Oral Presentation (MS26) Mechanisms Across Scales in Subsurface CO2 storage: A Special Session in Honor of Sally Benson MS26

Speaker

Brenda Maria De Castro Costa (PUC-Rio)

Description

Efficient carbon capture and sequestration (CCS) in deep saline aquifers relies on understanding the complex interactions between CO₂ and brine under varying conditions. Previous studies have provided critical insights into the mechanisms driving CO₂ storage. For instance, Wildenschild et al. [1] quantified the effects of interfacial tension, viscosity, and flow rate on capillary trapping, while Pentland et al [2]. measured the residual non-wetting phase saturations of supercritical CO₂, emphasizing capillary trapping as an effective immobilization mechanism. Furthermore, Peichung et al [3]. demonstrated how high-pressure microfluidic experiments enhance mass transfer rates, offering key insights into multiphase flow dynamics.

Considering relevant factors on these studies, we investigate the injection of CO₂ into a porous media micromodel, alternating with brine flooding, as a promising strategy to better understand carbon sequestration. This study examines the impact of pressure conditions—above and below the critical point of CO₂—on multiphase flow dynamics and CO₂ storage efficiency in saline aquifers. Using the Sapphire Lab microfluidic platform, we conduct controlled experiments that allow precise regulation of flow rate, pressure, and temperature, while simultaneously visualizing fluid behavior in the micromodel.

This approach enables real-time monitoring of aqueous phase saturation throughout the injection process, capturing the interplay between CO₂ and brine phases under diverse thermodynamic conditions. Key phenomena such as saturation, displacement patterns and capillary trapping are analyzed to understand the influence of sub- and supercritical pressures on fluid distribution and storage mechanisms.

Preliminary results reveal distinct behaviors at pressures above and below the critical point, with significant implications for optimizing injection strategies. High-resolution microfluidic techniques enhance the accuracy of multiphase flow observations, providing valuable insights for designing more efficient and sustainable carbon storage operations.

References [1] D. Wildenschild, R. T. Armstrong, A. L. Herring, I. M. Young, and J. W. Carey, “Exploring capillary trapping efficiency as a function of interfacial tension, viscosity, and flow rate,” Energy Procedia, vol. 4, pp. 4945–4952, 2011. [2] C. H. Pentland, R. El-Maghraby, A. Georgiadis, S. Iglauer, and M. J. Blunt, “Immiscible displacements and capillary trapping in CO2 storage,” Energy Procedia, vol. 4, pp. 4969–4976, 2011. [3] T. H. M. Ho, J. Yang, and P. A. Tsai, “Microfluidic mass transfer of CO2at elevated pressures: implications for carbon storage in deep saline aquifers,” Lab Chip, vol. 21, no. 20, pp. 3942–3951, 2021.
Country Brasil
Water & Porous Media Focused Abstracts This abstract is related to Water
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Primary authors

Brenda Maria De Castro Costa (PUC-Rio) Jorge Avendaño (Pontifical Catholic University of Rio de Janeiro PUC-Rio) Yan Salema de Medeiros (PUC-RIO)

Co-authors

Ms Daniela Hartmann (CNPC Brasil) Marcio Carvalho (PUC-Rio)

Presentation materials

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