19–22 May 2025
US/Mountain timezone

In-situ observation of mafic/ultramafic rock reactions with supercritical CO2 using neutron reflectometry

20 May 2025, 14:20
15m
Oral Presentation (MS25) Advances in Carbon Mineralization: Unveiling Multiscale Geo-processes and Coupled Mechanisms MS25

Speaker

Chelsea Neil (Los Alamos National Laboratory)

Description

Fast carbon dioxide (CO2) mineralization has been recently observed in mafic and ultramafic rocks, promoting CO2 stabilization and reducing risky reliance on caprock integrity. However, there are currently many unknowns surrounding these new observations, including reaction kinetics for different minerals. In the current study, we apply neutron reflectometry (NR) to make in situ observations of the fluid-rock interface to characterize these geochemical interactions for olivine, serpentine, and basalt thin films. We observed minimal reactivity for basalt compared with ultramafic minerals. Surprising, more alteration of serpentine was observed than olivine, despite reported lower reactivities. Through this work, we can advance our understanding of dissolution and secondary mineral precipitation during GCS in mafic/ultramafic rocks, which will allow optimization of CO2 mineralization through improved site selection and more accurate geochemical modeling.

Country USA
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Primary authors

Candice Halbert (Oak Ridge National Laboratory) Chelsea Neil (Los Alamos National Laboratory) Chris Keeter (Oak Ridge National Laboratory) Christopher Neal (Oak Ridge National Laboratory) Erik Watkins (Oak Ridge National Laboratory) Hari Viswanathan (Los Alamos National Laboratory) Jim Browning (Oak Ridge National Laboratory)

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