19–22 May 2025
US/Mountain timezone

Clean-up of granular aquifers: evaluation of in situ chemical oxidation processes by synchrotron-based X-ray microtomography

22 May 2025, 10:35
1h 30m
Poster Presentation (MS18) Innovative Methods for Characterization, Monitoring, and Remediation of Contaminated Soils and Aquifers Poster

Speaker

Nathaly Lopes Archilha (Brazilian Center for Research in Energy and Materials)

Description

In situ chemical oxidation (ISCO) has become a widely used remediation technique for contaminated areas due to its proven effectiveness. The use of potassium permanganate (KMnO4) to degrade trichloroethylene (TCE, C4HCl3) has demonstrated favorable results in both pilot- and field-scale studies. However, a key challenge in optimizing the process lies in the limited understanding of reactions at the microscale.

This work seeks to investigate the pore-scale dynamics of the ISCO remediation process of TCE using KMnO4. The study employs 3D synchrotron-based computed microtomography (µCT) to capture time-resolved images of an injection experiment conducted in a porous medium. Initial characterization of the water-saturated sample provided crucial data, including total porosity, grain surface area, and pore tortuosity. Analysis of samples saturated with TCE and KMnO4 revealed changes in permeability, residual contaminant levels, and the formation of reaction products.

Country Brasil
Water & Porous Media Focused Abstracts This abstract is related to Water
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Primary authors

Dr Daphne Silva Pino (Brazilian Synchrotron Light Laboratory) André Rodrigues Gomes Silva Nathaly Lopes Archilha (Brazilian Center for Research in Energy and Materials)

Co-authors

Carlo Bianco (Politecnico di Torino - DIATI) Luiz Fernando de Lima Luz Junior (Federal University of Paraná) Tannaz Pak (Teesside University)

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