19–22 May 2025
US/Mountain timezone

Pore-scale Analysis of Carbonate Acidification Based on CT Scan Imaging: An Experimental Investigation

21 May 2025, 11:50
15m
Oral Presentation (MS12) Advances in computational and experimental poromechanics MS12

Speaker

Victoria Farçal Rocha da Costa (Federal University of Pernambuco)

Description

Well-stimulation techniques are designed to mitigate formation damage phenomena. Matrix acidizing, a standard stimulation method, involves injecting an acidic fluid into the formation near the well to dissolve rock matrix minerals, create dissolution channels, enhance permeability, and restore well flow. Hydrochloric acid (HCl) is the most commonly used acid for this purpose; however, its high reaction rate with carbonates can limit its penetration into the formation. To optimize acid usage and increase the depth of wormholes, it is crucial to develop stimulation fluids with additives that slow down the acid’s dissolution of the rock matrix.
This study aimed to understand the impact of stimulation fluids on the rock's petrophysical and geomechanical properties. Computed microtomography (µCT) was employed to analyze the resulting wormhole patterns. Key characterizations included reactive fluid properties, carbonate rock samples, porosity and permeability measurements, rock mechanics tests, porous media flow tests, and X-ray µCT imaging.
The results revealed significant weakening and stiffness loss in the rock after acid treatment. Samples treated with 15% HCl exhibited Young’s modulus values approximately 96% lower than those of the intact samples, while those treated with 15% HCl plus additives showed a 22% reduction. Conversely, the 15% HCl group displayed a Poisson’s ratio 39% higher than the intact samples, compared to a 15% increase for the additive group. The uniaxial compressive strength (UCS) of the 15% HCl group was around 60% lower than that of the intact samples, whereas the additive group showed an 8% reduction. Similarly, diametral compressive strength for the 15% HCl-treated samples was approximately 17% of the UCS, while the additive-treated samples achieved about 8%.
Micro-computed tomography visually confirmed the creation of fluid flow pathways from the reservoir to the well due to acid treatment. Rock mechanics findings highlighted that samples treated with 15% HCl and additives suffered less damage to their rock matrix than those treated with 15% HCl alone.

References CHANG, F.; FOGLER, H. S. Carbonate Acidizing. In: ALI, S. A.; KALFAYAN, L.; MONTGOMERY, C. T. Acid Stimulation. Richardson: Society of Petroleum Engineers, p. 120–161. 2016. FELDKAMP, L. A.; DAVIS, L. C.; KRESS, J. W. Practical Cone-Beam Algorithm. Journal of the Optical Society of America A, v: 1, n. 6, p. 612. 1984. GARROUCH, A. A.; JENNINGS, A. R. A Contemporary Approach To Carbonate Matrix Acidizing. Journal of Petroleum Science and Engineering, v. 158, p. 129–143. 2017. GHOMMEM M, ZHAO W, DYER S, QIU X, BRADY D. Carbonate Acidizing: Modeling, Analysis, And Characterization Of Wormhole Formation And Propagation. Journal of Petroleum Science and Engineering. v: 131, p. 18–33. 2015. HOEFNER, M. L.; FOGLER, H. S. Pore Evolution and Channel Formation during Flow and Reaction in Porous Media. AIChE Journal, v: 34, n. 1, pp. 45–54. 1988. LIU M, MOSTAGHIMI P. Pore-Scale Simulation Of Dissolution-Induced Variations In Rock Mechanical Properties. International Journal of Heat and Mass Transfer. v: 111, p. 842–851.
Country Brazil
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Primary author

Victoria Farçal Rocha da Costa (Federal University of Pernambuco)

Co-author

Leonardo José do Nascimento Guimarães

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